Печать

O.U. Gapurova, R.R. Khaidarov, I.G. Galiulin

NEW FIBROUS ION-EXCHANGE SORBENTS FOR WATER PURIFICATION

Abstract. The aim of this study was to reduce pollution in water purification systems using fibrous ion-exchange sorbents. A method for modifying a mixed polyester material and polyacrylonitrile threads to obtain these sorbents using available and inexpensive preparations has been developed. Obtaining cation-exchange sorbents included treating the fibers with a 5 % NaOH solution at a temperature of 40-80 °C and a 25 % NH2NH2H2O solution at a temperature of 70-90 °C. Anion-exchange sorbents were obtained by treating cation-exchange sorbents with a 1-5 % polyethyleneimine solution, as well as additionally treating with a 1% epichlorohydrin solution at a room temperature of 30 °C. These sorbents can be used to remove radionuclides, heavy metal ions, and organic contaminants from wastewater and drinking water. The sorption properties of these sorbents and their ability to remove 57Co, 60Co, 65Zn, 90Sr, 134Cs, 137Cs, and other radionuclides, heavy metal ions (Zn, Ni, Cu, Pb, Cd, Cr, etc.) from aqueous media were studied. The static exchange capacity was 1–2 mg-eq/g for cation-exchange sorbents and 0.45–0.8 mg-eq/g for anion-exchange sorbents.

Keywords: polyester, polyacrylonitrile fibers, cation exchange, anion exchange, fibrous sorbent, water purification.

For citation: Gapurova O.U., Khaidarov R.R., Galiulin I.G. [New fibrous ion-exchange sorbents for water purification] Upravlenie tekhnosferoi, 2025, vol. 8, issue 3, рр. 421 – 438. (In Russ.). DOI: 10.35634/UdSU.2025.31.73.005

REFERENCES

 

  1. Khaydarov R.R et al. The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures, Journal of Energy, Environmental & Chemical Engineering, 2020, 5(1), pp. 10 – 13.
  2. Zverev M.P. Khemosorbtsionnye volokna [Chemisorption fibers]. Moscow: Chemistry, 1981, 191 p. (In Russ.).
  3. Nemilova T.V., Emets L.V., Nemilov V.N. et al. Novye kompleksoobrazuyushchie sorbenty na osnove poliakrilonitril'nykh volokon [New complexing sorbents based on polyacrylonitrile fibers]. Khim. volokna, 1996, no. 6, р 22 – 26. (In Russ.).
  4. Khaydarov R.R et al. Fibroid Sorbents for Water Purification, in Modern Tools and Methods of Water Treatment for Improving Living Standards, 1V. Earth and Environmental Sciences, 2005, vol. 48, pp. 101 – 108.
  5. Khaydarov R.R, Khaydarov R.A. Purification of drinking water from 134, 137Cs, 89, 90Sr, 60Co and 129I, in Medical Treatment of Intoxication and Decontamination of Chemical Agent in the Area of Terrorist Attack, Series –A: Chemistry and Biology, 2006, vol. 1, pp.171 – 181.
  6. Khaydarov R.R, Khaydarov R.A. Environmental Change in the Aral Sea Region: New Approaches to Water Treatment in Environmental Change and Human Security: Recognizing and Acting on Hazard Impacts, Series C: Environmental Security, Springer Netherlands, 2008, pp.433 – 447.
  7. Khaydarov R.R, Khaydarov R.A., Cho S. Natural disaster: Prevention of drinking water scarcity, Threats to Global Water Security, (Jones, J. et. al.: Eds.), Springer, Netherlands, 2009, pp. 381 – 384.
  8. Zverev M.P. Khimiya volokon [Chemistry of fibers]. 25:498. doi:10.1007/BF00550794, 1994. (In Russ.).
  9. Ashirov A. Ionoobmennaya ochistka stochnykh vod, rastvorov i gazov [Ion-exchange purification of wastewater, solutions and gases]. Leningrad: Chemistry, 1983, 295 p. (In Russ.).

 

About the Authors

Gapurova Olga Urumbaevna

Candidate of Chemical Sciences, Junior Researcher, Institute of Nuclear Physics, Academy of Sciences of the Republic of Uzbekistan, 100214, Tashkent, Uzbekistan.

E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.

Khaidarov Renat Rashidovich

Candidate of Physical and Mathematical Sciences, Head. Laboratory of Interdisciplinary Technologies, Institute of Nuclear Physics, Academy of Sciences of the Republic of Uzbekistan, 100214, Tashkent, Uzbekistan.

E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.

Galiulin Ildar Galievich

Junior Researcher, Institute of Nuclear Physics, Academy of Sciences of the Republic of Uzbekistan, 100214, Tashkent, Uzbekistan.

E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.

 

Full-text version - pdf(521kb)