M.A. Pashkevich, D.A. Patokin

 

MINERAL IMPROVEMENTS BASED ON INDUSTRIAL WASTE CONTAINING NITRIC ETHERS OF CELLULOSE

 

Annotation. Waste management has become one of the priority tasks in the framework of the country's economic development in recent years. Waste recycling, which involves the production of finished products from secondary resources, occupies an important place in the system of production and consumption waste management. Subsectors of the chemical industry, accumulating significant amounts of nitrocellulose-containing waste, become a possible source of secondary raw materials for obtaining ameliorants based on them due to their chemical composition. The aim of the study was to obtain effective and environmentally friendly mineral ameliorants based on nitrocellulose-containing waste. A chemical analysis of the waste was carried out using the methods of X-ray fluorescence analysis and IR spectroscopy with the establishment of a hazard class for the environment. Solutions of alkalis and acids for the destruction of cellulose nitrates in the waste were selected, and its disposal was carried out. Based on the results of destruction, samples of mineral ameliorants were obtained with the determination of their chemical composition by similar methods and the calculation of the hazard class for the environment. Empirically, based on the calculation of the doses of ameliorants and the germination of grass mixtures, the effectiveness of their introduction was established on the example of podzolic soils.

Keywords: waste management, cellulose nitrates, nitrocellulose, recycling, ameliorant, sewage sludge, reclamation.

 

For citation: Pashkevich M.A., Patokin D.A. [Mineral ameliorants based on industrial wastes containing cellulose nitrate esters] Upravlenie tekhnosferoi, 2023, vol. 6, issue 3. (In Russ.) Available at: https://technosphere-ing.ru/ рр. 386–402. DOI: 10.34828/UdSU.2023.62.58.007

References

  1. Ohrana okruzhajushhej sredy v Rossii. [Environmental protection in Russia]. Moscow, Rosstat, 2022. 115 p. (In Russ.).
  2. Hozin V.G., Cyganova E.A. Rol' stroitel'noj industrii v realizacii federal'nogo proekta «Jekonomika zamknutogo cikla» [Role of the construction industry in the implementation of a federal project «The closed-cycle economy». Jekspert: teorija i praktika [Expert: theory and practice], 2023, no.1(20), pp. 147–159. (In Russ.).
  3. Zabelin L.V., Gafijatullin R.V., Kuz'mickij G.Je. Zashhita okruzhajushhej sredy v proizvodstve porohov i tverdyh raketnyh topliv [Environmental protection in the production of gunpowder and solid rocket fuels]. Moscow, Nedra, 2002, 174 p. (In Russ.).
  4. Valishina Z.T. Obezvrezhivanie osadkov tehnologicheskih stochnyh vod proizvodstva nitratov celljulozy. Soobshhenie 2. [Neutralization of precipitation of technological wastewater from the production of cellulose nitrates. Message 2.]. Vestnik tehnologicheskogo universiteta [Herald of technological university]. 2017, vol. 20, no. 9, pp. 140–143. (In Russ.).
  5. Cherenkov P.G. Tehnologija ajerobnoj pererabotki nitrocelljulozosoderzhashhih osadkov stochnyh vod porohovyh proizvodstv s polucheniem organo-mineral'nyh pochvogruntov [Technology of aerobic processing of nitro cellulose-containing sewage sludge from powder industries with the production of organo-mineral soils]. Vestnik tehnologicheskogo universiteta [Herald of technological university]. 2015, vol. 18, no. 12, pp. 51–53. (In Russ.).
  6. Demakov V.A. Izuchenie processov mikrobnogo metabolizma organicheskih nitrosoedinenij i razrabotka jeffektivnogo biokatalizatora dlja ih biotransformacii i biodegradacii [Study of the processes of microbial metabolism of organic nitro compounds and development of an effective biocatalyst for their biotransformation and biodegradation]. Vestnik Permskogo federal'nogo issledovatel'skogo centra [Perm Federal Research Centre UB RAS], 2020, no. 2. pp. 23–35. (In Russ.).
  7. Saratovskih E.A. Destrukcija nitrovannoj celljulozy gribami Fusarium solani [Destruction of nitrated cellulose by Fusarium solani fungi]. Prikladnaja biohimija i mikrobiologija [Applied Biochemistry and Microbiology], 2018, vol.54, no.1, pp. 55–62. (In Russ.).
  8. Kolmakov K.M. Himicheskaja utilizacija othodov nitratov celljulozy [Chemical disposal of cellulose nitrate waste]. Himicheskaja fizika [Chemical physics], 2017, vol. 36, no. 8, pp. 75–81 (In Russ.).
  9. Petrova T.A., Rudzish Je. Vidy meliorantov dlja rekul'tivacii tehnogenno narushennyh territorij gornoj promyshlennosti [Types of soil improvers for reclamation of mining-disturbed lands]. Gornyj informacionno-analiticheskij bjulleten' [Mining information and analytical bulletin], 2021, no 4, pp. 100–112. (In Russ.).
  10. The use of soil based on sewage sludge from urban wastewater treatment plants in the greening of urban areas. A.V.Ilinskiy, V.N.Selmen, E.V.Selmen [et al.]. Theoretical and Applied Ecology, 2022, no. 2, pp. 191–
  11. Matjuhin M.S. Opyt utilizacii osadka stochnyh vod [Experience in disposal of sewage sludge]. Plodorodie [Fertility], 2018, no.4 (103), pp. 56–58. (In Russ.).
  12. Valiev V.S., Ivanov D.V., Shagidullin R.R. Analiz mirovogo opyta utilizacii osadka gorodskih stochnyh vod [Analysis of the world experience in the disposal of urban sewage sludge]. Rossijskij zhurnal prikladnoj jekologii [Russian Journal of Applied Ecology], 2020, no. 4(24), pp. 43–51. (In Russ.).
  13. Komarova E.V., Komarova A.V., Slabunova A.V. Sovremennye problemy primenenija othodov zhivotnovodstva v kachestve udobrenija: analiz pravovogo polja [Modern problems of using animal husbandry waste as fertilizer: analysis of the legal field]. Jekologija i vodnoe hozjajstvo [Ecology and water management], 2021, vol.3, no.4, pp. 27–45. (In Russ.).
  14. Bondarenko A.M., Kachanova L.S. Jekonomiko-tehnologicheskaja jeffektivnost' processov reciklinga organicheskih othodov v obespechenii ustojchivosti agrarnogo sektora [Economic and technological efficiency of organic waste recycling processes in ensuring the sustainability of the agricultural sector]. Moskovskij jekonomicheskij zhurnal [Moscow Economic Journal], 2020, no. 8, pp. 126–133. (In Russ.).
  15. Sabitov K.B., Muhametov A.A., Husainova K.G. Razrabotka i primenenie v polevodstve kompleksnyh mineral'nyh udobrenij iz othodov sodovogo proizvodstva [Development and application of complex mineral fertilizers from soda production waste in field production]. Izvestija Orenburgskogo gosudarstvennogo agrarnogo universiteta [Proceedings of the Orenburg State Agrarian University], 2020, no. 3(83), pp. 18–23. (In Russ.).
  16. Litvinova T.E., Suchkov D.V. Kompleksnyj podhod k utilizacii tehnogennyh othodov mineral'no-syr'evogo kompleksa [Comprehensive approach to the utilisation of technogenic waste from the mineral resource complex]. Gornyj informacionno-analiticheskij bjulleten' [Mining information and analytical bulletin], 2022, no.6-1, pp. 331–348. (In Russ.).
  17. Safronov V.P., Matychenkov V.V., Bocharnikova E.A. et all. Proizvodstvo pochvennyh meliorantov na osnove organicheskih othodov promyshlennosti v processe ih utilizacii v otvalah ugol'nyh kar'erov [Production of soil ameliorants based on organic industrial waste in the process of their disposal in the dumps of coal pits]. Izvestija Tul'skogo gosudarstvennogo universiteta. Nauki o Zemle. [Izvestiya Tula State University], 2018, no. 4, pp. 22–32. (In Russ.).
  18. Petrova T.A. Rekul'tivacija tehnogenno-narushennyh zemel' s primeneniem osadkov stochnyh vod v kachestve meliorantov [Utilization of sewage sludge as an ameliorant for reclamation of technogenically disturbed lands]. Zapiski Gornogo instituta [Journal of Mining Institute]. 2021, vol. 251, pp. 767–776. (In Russ.).
  19. Zhegrov E.F., Miljohin Ju.M., Berkovskaja E.V. Himija i tehnologija ballistitnyh porohov, tvjordyh raketnyh i special'nyh topliv. [Chemistry and technology of ballistic powders, solid rocket and special fuels.] Technology: Monograph, Moscow, RIC MGUP im. Fedorova, 2011, pp. 551. (In Russ.).
  • Petrova T.A., Rudzish Je. Metod ocenki jeffektivnosti meliorantov pri rekul'tivacii narushennyh zemel' [Method for assessing the effectiveness of ameliorants in the reclamation of disturbed lands]. Vestnik evrazijskoj nauki [The Eurasian Scientific Journal], 2021, vol. 13, no. 6. Avialable at: https://esj.today/PDF/53NZVN621.pdf (In Russ.).

 

About the Authors

Pashkevich Mariya Anatolievna

Doctor of Engineering Sciences, Professor of the department of geoecology, Federal State Budgetary Educational Institution of Higher Education «Saint Petersburg Mining University», 199106, Vasilievsky Istland, 21 line, 2, St. Petersburg, Russia.

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Patokin Dmitry Aleksandrovich

Postgraduate student of the department of geoecology, Federal State Budgetary Educational Institution of Higher Education «Saint Petersburg Mining University», 199106, Vasilievsky Istland, 21 line, 2, St. Petersburg, Russia.

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